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Chemical researchers invent bio-petroleum for sustainable materials

Chemical researchers invent bio-petroleum for sustainable materials

Led by CSP Investigators Michelle Chang and Paul Dauenhauer, researchers have developed a two-step pathway to produce petroleum-like liquids from renewable materials, such as glucose.

The hybrid approach combines fermentation and chemical synthesis, and it has the benefit of competing economically with conventional products derived from fossil fuels, while also improving sustainability. Technologies were integrated to find the lowest-energy and lowest-cost processing techniques leading to the most overall efficient method of making chemicals.

“This advance from the NSF Center for Sustainable Polymers demonstrates a truly innovative, green entry into the building blocks for valuable polymers/plastics,” said NSF Chemistry Division Director David Berkowitz. “By cleverly combining biology and chemistry, the Chang team has opened a new, potential bio-renewable alternative to petroleum cracking. These results showcase how NSF investments in collaborative, interdisciplinary science can push the envelope toward developing more sustainable chemical industries.”

These renewable liquids could serve as a more sustainable replacement for today’s fossil fuels used to make everyday products like plastic containers and bags, automobile parts, lubricants, and soaps.

https://csp.umn.edu/

New TPE solution complies with global food-contact regulations

New TPE solution complies with global food-contact regulations

KRAIBURG TPE, a global TPE manufacturer of a diverse range of thermoplastic elastomer products and custom solutions for a variety of industries, offers the new THERMOLAST® K FC/AD/PP series for food contact applications

Today’s consumers are seeking products and brands that align with their health and safety values by making informed decisions prior to their purchase. This shift in consumer behavior has prompted manufacturers to ensure adherence and compliancy with national and international food safety regulations to attract more customers.

Consumers have the right to expect that the products they purchase will be safe and of high quality. That is why manufacturers have to ensure that the materials used in the production of such goods do indeed meet consumer expectations of safety and quality. It is for this reason that food-contact safe materials such as thermoplastic elastomers (TPEs) are fast gaining popularity.

Enter KRAIBURG TPE with its new THERMOLAST® K FC/AD/PP food- contact safe and regulation-compliant TPE series for a wide scope of consumer product applications.

Complying with various global food contact standards

‘Ensuring consumer safety is crucial for today’s consumer products manufacturers,’ states Lee Jia Yin, Product Developer at KRAIBURG TPE. She adds that KRAIBURG TPE’s new FC/AD/PP series satisfies food safety material requirements, and meets stringent regulatory criteria, including (EU)

No. 10/2011, GB 4806-2016, and (FDA) CFR Title 21. The series also complies with the DIN EN 71-3 toy specifications, as well as the REACH, SVHC and RoHS.

Material solution for everyday consumer applications KRAIBURG TPE’s FC/AD/PP series features properties such as PP adhesion, optimized flow, and hardness range from 30 to 90 Shore A. The materials are easily processable by injection molding, extrusion and 3D printing.

Furthermore, the compounds in the FC/AD/PP series are free from animal ingredients, heavy metals, phthalates, bisphenol A, and latex, accommodating to the production of sustainable goods.

The compounds are available in natural and translucent colors with the option of in-house pre-coloring, allowing the flexibility of a variety of product solutions.

The superior haptics and soft-touch features of KRAIBURG TPE’s new FC/AD/PP series of compounds are ideal for applications such as household goods, packaging for food and consumer care articles, razors, toothbrushes, toys and other products.

UniteChem expands its portfolio of high- performance light stabilizers

UniteChem expands its portfolio of high-performance light stabilizers

Dusseldorf, Germany, November 3, 2021 – UniteChem Group, the world’s leading supplier of light stabilizers for plastics in a broad range of high-end industrial applications, has recently started full-scale production of advanced high-performance light stabilizers UniteChem LS2020 and LS119 in its newly commissioned production facilities.

“UniteChem Group began producing industry-standard light stabilizers such as UniteChem LS944 in 1997 and has been continuously expanding its polymer additives portfolio ever since”, says Junyi Lin, CEO of UniteChem Group. “Today, we are proud to be among the world’s largest- capacity suppliers of light stabilizers and other plastic additives, offering over 40’000 tons of finished products. Our full backward integration with a production capacity of over 80’000 tons of intermediates provides extensive production flexibility, high reliability, and maximum quality control. Current production, located in two state-of-the-art production facilities in Jiangsu province, is now in process of being complimented with two new major production facilities in Jiangsu and Sichuan provinces, with completion in 2022/23.”

UniteChem LS2020 is a modern HALS (hindered amine light stabilizer) offering excellent anti-aging properties in applications such as cross-linked polyethylene, olefin copolymers and other polymer materials. UniteChem LS119 is especially suited for use in polyethylene greenhouse film applications, polypropylene fibers, TPO automotive parts as well as other polymers such as EVA, EPDM, PA, PET and PMMA. With these product additions, UniteChem Group further enhances its commitment to offer customers the most up-to-date and value-added product portfolio.

Junyi Lin added: “The production of UniteChem LS2020 and LS119 is currently being methodically ramped up, with target capacities of 1’000 tons and 2’000 tons annually to meet global demand.”

As part of its commitment to invest in future solutions for its customers, UniteChem Group regularly allocates five percent of its total revenue to R&D, operating five independent laboratories – including its recently opened modern Shanghai R&D Center. Current efforts focus on expanding the group’s portfolio with high-demand UV Absorbers, NOR-HALS light stabilizers as well as other key polymer additives.

FROM TREES TO BATTERIES

FROM TREES TO BATTERIES

At Stora Enso, we believe that everything that is made from fossil-based materials today can be made from a tree tomorrow. As another proof of this, we produce bio-based carbon called Lignode® by Stora Enso, used for sustainable electrification. Our aim is to meet the demands of the global battery market by developing renewable alternatives.

The battery market is projected to increase tenfold in the next ten years, especially due to increasing e-mobility solutions, such as electric cars, buses and bicycles. Synthetic graphite, a non-renewable, fossil-based material commonly used in batteries, can be replaced by lignin. Lignin makes up 20–30% of a tree and is a by-product in the production of cellulose fiber. It is one of the largest renewable sources of carbon anywhere, is traceable, and millions of tonnes of it are already being produced in Europe. Stora Enso is the largest kraft lignin producer in Europe, with an annual lignin production capacity of 50,000 tonnes.

Meeting the eco-friendly mindset of future customers

Lignin-based carbon can be used in batteries, typically those used in consumer electronics and the automotive industry, and in large-scale energy storage systems. Stora Enso uses dry lignin to manufacture Lignode and aims to create a European supply chain for the lithium-ion battery industry. Our target is to offer the most sustainable and lowest-impact anode material available, to meet the eco-friendly mindset of future consumers. Our lignin has superior traceability with sustainable raw-material management certificates.

Lignin-based carbon belongs to the category of so-called hard carbons, which were the basis for initial developments in Li-ion battery technologies. Hard carbons from lignin can be compared to other non-graphitic carbon anode materials. The structure of hard carbon in Lignode enable the anode in a battery to be charged and discharged more quickly, compared to traditional graphite. It also allows for better performance at lower temperatures, and is therefore less prone to safety risks in temperatures below freezing.

Together for a fossil-free future

As we know, innovation does not happen in isolation. To serve the fast-growing anode materials market, we are now exploring strategic partnerships to accelerate scale-up and commercialisation to drive self-sufficiency in the European battery supply chain.

The pilot plant for bio-based carbon materials is located at Stora Enso’s Sunila production site in Finland, where lignin has been industrially produced since 2015. The biorefinery’s annual lignin production capacity is 50,000 tonnes, making Stora Enso the largest kraft lignin producer in the world.

https://www.storaenso.com/

A new Advanced Bio-Circular medical polymer for medical

A new Advanced Bio-Circular medical polymer for medical

With a proven legacy in high performance materials for medical applications, Arkema now announces the launch of a new high rigidity Advanced Bio-Circular polyamide 11 medical polymer intended to replace metal and traditional polymers in demanding medical applications.

Arkema’s Advanced Bio-Circular (ABC) materials have a long, proven legacy in some of the world’s most demanding applications. These bio-based, recyclable polymers are derived from Arkema’s flagship amino 11 chemistry, which in turn, is derived from the oil of the renewable castor bean. Castor beans do not compete directly with the food chain and do not cause deforestation.

Formulated with a high content (65%) of glass fibers, the new Rilsan® MED polyamide 11 grade displays a tensile modulus of 18.5GPa, making it an ideal candidate to replace metal for the production of highly demanding surgical tools.

The new grade also requires low mold temperatures and injection pressures. Those properties helped early adopters to switch materials easily and to decrease their cycle times significantly whilst maintaining component integrity.

Furthermore, this new material exhibits excellent resistance to gamma, steam, ETO and e-beam sterilization, opening new doors and opportunities for the development of sustainable reusable surgical tools and for the replacement of petroleum based polymers.

The biocompatibility of this new product has been successfully assessed according to USP Class VI, ISO 10993-4, ISO 10993-5 and ISO 10993-10 standards.

We have found in this new product an ideal material for our surgical tools, easier to process than the PARA (Polyarylamide) we were using before. Its bio-based nature has given us a real advantage to answer our customer’s drive towards more sustainable materials.”
 

MARK JESSUP, MANAGING DIRECTOR AT SURGICAL DYNAMICS, ONE OF THE EARLY ADOPTERS OF THIS NEW RILSAN® MED
 

Arkema continues to innovate to offer sustainable and recyclable materials, based on our proprietary polyamide 11 chemistry, to the most demanding and challenging markets. Our medical device customers are becoming more and more vocal on sustainability and Arkema is extremely well positioned to successfully help them transition to renewable materials and reaching their goals to reduce natural resource depletion.”
 

FRANÇOIS RUAS, HEALTH & BEAUTY GLOBAL MARKET MANAGER, ARKEMA HIGH PERFORMANCE POLYMERS
 

Fate of billions of plastic bottles potentially altered through ground-breaking Amcor technology

Fate of billions of plastic bottles potentially altered through ground-breaking Amcor technology

Amcor Rigid Packaging announces recycling innovation that will enable more than a billion 50 mL spirits bottles to be crushed, captured and recycled.
 

In conjunction with America Recycles Day, Amcor Rigid Packaging (ARP) is announcing a technological advancement that makes it possible for billions* of small bottles to be recycled. ARP, known for its designed-to-be-recycled packaging, is always looking for ways to increase the amount of material that makes it to – and through – the recycling process.

ARP is first applying the technology to 50 mL spirits bottles. These bottles, while made of recyclable polyethylene terephthalate (PET), are often lost in the recycling process due to their small size. Most people recognize these as the little liquor bottles often served on airplanes. Despite its material being infinitely recyclable**, the size of these bottles presents challenges at most U.S. material recycling facilities. The bottles tend to slip out of the sorting process where broken glass is filtered out for disposal.

“We know that many small bottles are falling through screens in our MRFs designed to separate glass, so this is a major development – it allows these bottles to pass this step in the process and have the opportunity to be captured by the appropriate equipment downstream. At a time when the recycling industry is constrained by material supply every additional pound diverted from waste makes a big difference,” said Curt Cozart of the Association of Plastic Recyclers.

With its pledge to develop all its packaging to be recyclable, compostable or reusable by 2025, Amcor is always innovating to increase the recyclability of its products. Seeing an opportunity for improvement, ARP’s team of engineers examined the issue and began designing a container that collapses in a controlled way to maximize its width. With a collapsed width greater than 5 cm, this design would no longer slip through the cracks at most U.S. recycling facilities.

“This discovery was made by the Amcor team when testing revealed that the bottles collapse in different ways,” said Terry Patcheak, VP of Research & Development and Advanced Engineering at ARP. “Our simulations demonstrated that when these tiny spirits bottles are designed to collapse in a specific way, fewer bottles actually fall through the cracks. The potential here is higher recyclability rates and more recycled content for multiple segments and materials.”

Amcor’s bottle design includes intentional failure points and is based on the Association of Plastic Recyclers specific guidelines. Finite Element Analysis testing is being undertaken to better understand the dynamics of these small bottles during the recycling process. Additionally, ARP will partner with recycling facilities to capture real-world data about the recyclability of its new bottle.

“We look forward to seeing the data and continuing to use this kind of creative approach to look at all of our packaging. In partnering with the APR, we are looking at size, color and material to increase the amount of recycled material that can be turned into more bottles. We look forward to partnering with our customers as we use a new lens to look at ways to meet our shared sustainability goals,” Patcheak said.

https://www.amcor.com/

Microwave-Based Direct Monomerization Project for Plastic Waste

Microwave-Based Direct Monomerization Project for Plastic Waste

Aiming to commercialize chemical recycling of hard-to-recycle ASR and SMC

Mitsui Chemicals, Inc.and Microwave Chemical Co. Ltd have launched a new initiative aimed at commercializing the use of microwave technology in the chemical recycling of plastic waste. The project involves directly producing raw monomers from plastics that have conventionally been tricky to recycle, including automotive shredder residue (ASR) – a mixture of principally polypropylene-based plastics – and thermosetting sheet molding compound (SMC), which is used in bathtubs and vehicle parts.

Since entering into a strategic partnership in 2017 to promote joint development of next-generation chemical process technologies, Mitsui Chemicals and Microwave Chemical have built up a solid relationship, including through partial equity investment. The two companies are together looking at leveraging microwave technology for a variety of chemical processes.

This new initiative is an attempt to commercialize a chemical recycling technique that uses the PlaWave™ microwave-based plastic degradation technology developed by Microwave Chemical to directly break down ASR and SMC products into raw monomers. As it eliminates an intermediate step, direct monomerization is a more efficient means of recycling plastic waste into plastic than the conventional approach, which involves turning the waste into oil before monomerization. The technique also promises to reduce CO2 emissions through the use of electricity generated from renewable energy to power the decomposition process.

With initial deliberations having yielded positive results, the project will proceed to verification using Microwave Chemical’s bench-scale equipment before the end of fiscal 2021. A move to full implementation will be then be considered with the objective of promptly commencing demonstration tests.

Microwaves are an electromagnetic wave which is frequently used for microwave oven and communication applications, which can transfer energy to materials directly and selectively. As microwaves can be generated from renewable energy sources, this technology is environmentally friendly, which promotes a reduction of CO2 emissions

https://jp.mitsuichemicals.com/

Carbon Makes Design Engine™ Software Available to All

Carbon Makes Design Engine™ Software Available to All

 
 Carbon, a leading 3D printing technology company, announced today that it is launching the next generation of its Carbon Design Engine™ software and making the software licenses available to design teams globally for purchase in early 2022.

Carbon Design Engine allows product designers to generate advanced latticed parts quickly and easily from a solid part STL file and output STL files for printing on most common 3D printers. Previously, this software was available only to Carbon platform customers, but beginning in early 2022 software licenses will be available for individuals and teams to design, develop, and print advanced lattices on most common 3D printers. With broad accessibility to Carbon’s lattice-generating design software, design engineers and industrial designers can automate the process of creating conformal, multi-zone lattices, dramatically accelerating the product development process. Design Engine has been widely used by global brands to design high-performance, breakthrough products, including bike saddles, helmets, and sporting gloves.

Specialized Bicycles reimagined the bike saddle leveraging Carbon Design Engine. “We’ve invested heavily in research and innovation, with the goal of improving riders’ experience on the bike. Our collaboration using Carbon’s Design Engine software and 3D printing process enabled us to develop a saddle with different damping characteristics, something impossible with traditional foam, leading to superior comfort. We wanted to push the limits and our partnership with Carbon allowed us to do just that,” said Emma Boutcher, Saddles, Grips and Tapes Product Manager at Specialized.

Carbon’s idea-to-production platform enables creators to develop better products in less time. It is comprised of a wide range of materials, a suite of software to design products and define production processes, and high-speed 3D printers. Within Carbon’s software suite, Design Engine automates complex product design and development from prototyping to production. Innovative products designed with Design Engine have successfully moved from design to production in months and then been produced at scale.

“Creators are challenged with fragmented solutions and organizational silos that have caused friction, limitations on innovation, and delayed time to market. To successfully bring better products to market in less time, organizations need a platform that unifies product design, development, and manufacturing,” said Phil DeSimone, Chief Product and Business Development Officer at Carbon. “Carbon’s software suite, starting with Design Engine, aims to cover every step needed for companies to create products with superior performance while accelerating the time to market.”

Lattice structures require less material, while retaining tunable mechanical properties. As a result, latticed parts can provide performance advantages, including lightweighting, flexibility, improved cushioning and dampening, heat dissipation, and unique aesthetics. Because of Design Engine’s unique ability to run complex computations in the cloud, design engineers can experience extremely fast design cycles to rapidly refine lattice designs in minutes, and use most 3D printers to manufacture them immediately. As a result, this robust and powerful tool helps creators go from idea to functional lattice part in hours, rather than days.

Key features of Design Engine include:

  • Multi-zone: The Pro tier of Design Engine introduces the ability to tune multiple zones at once, integrating different lattice types, cell sizes, or strut diameters to create different zones of performance within a single part, using the same material.
  • Powerful zone transitions: The Pro tier of Design Engine uses patent-pending technology to seamlessly blend zones, producing attractive, functional lattices ready to use in real-world applications.
  • No tedious tuning: Designing even simple lattices often requires tedious, manual work that is prone to errors that can significantly impact part performance. Design Engine resolves lattice features, both large and small, while robustly transitioning seamlessly between different zones inside the same part for tunable performance.
  • Precise control: Lattices generated in Design Engine can be optimized for a wide array of performance characteristics, including part volume and tunable mechanical response.
  • Compatibility: Design Engine offers compatibility with most common additive manufacturing techniques by outputting generated lattices as STLs.

“Carbon’s move to open its design software to all designers is a game-changer for the product development process. We’ve seen what innovative designs are possible with Design Engine, and heard real use cases of efficiency from idea-to-production,” said Tim Greene, a Research Director at IDC. ”Moreover, the ability to generate designs that are agnostic to many printer technologies will empower more teams to rapidly create functional latticed parts.”

https://www.carbon3d.com/

Electric vehicles could fully recharge in under 5 minutes with new charging station cable design

Electric vehicles could fully recharge in under 5 minutes with new charging station cable design

Purdue University engineers have invented a new, patent-pending charging station cable that would fully recharge certain electric vehicles in under five minutes – about the same amount of time it takes to fill up a gas tank.

Today, chargers are limited in how quickly they can charge an EV’s battery due to the danger of overheating. To charge an EV faster, a higher current needs to travel through the charging cable. The higher the current, the greater amount of heat that must be removed to keep the charging cable operational. The cooling systems that chargers currently use remove only so much heat.

Using an alternative cooling method, Purdue researchers designed a charging cable that can deliver a current 4.6 times that of the fastest available EV chargers on the market today by removing up to 24.22 kilowatts of heat. The project was funded by a research and development alliance between Ford Motor Co. and Purdue.

Electric vehicle charging time can vary widely today, from 20 minutes at a station alongside a roadway to hours using an at-home charging station. Wait times and charger location are both cited as major sources of anxiety for people who are considering electric vehicle ownership.

“My lab specializes in coming up with solutions for situations where the amounts of heat that are produced are way beyond the capabilities of today’s technologies to remove,” said Issam Mudawar, Purdue’s Betty Ruth and Milton B. Hollander Family Professor of Mechanical Engineering.

“Ford is committed to making the transition to electrification easy,” said Matt Stover, director of charging, energy services and business development at Ford. “We are glad to support Purdue’s research, which has the potential to make electric vehicle and commercial fleet ownership more appealing and accessible.”

Though the prototype hasn’t been tested on EVs yet, Mudawar and his students demonstrated in the lab that their prototype accommodates a current of over 2,400 amperes – far beyond the 1,400-ampere minimum that would be needed to reduce charging times for large commercial EVs to five minutes. The most advanced chargers in the industry deliver only currents up to 520 amperes, and most chargers available to consumers support currents of less than 150 amperes.

Ultimately, charge times will be dependent on the power output ratings of the power supply and charging cable, and the power input rating of the EV’s battery. To obtain a sub-five minute charge, all three components will need to be rated to 2,500 amperes.

The prototype also mimics all the traits of a real-world charging station: It includes a pump, a tube with the same diameter as an actual charging cable, the same controls and instrumentation, and it has the same flow rates and temperatures.

Mudawar’s lab intends to work with EV or charging cable manufacturers to test the prototype on EVs within the next two years. The testing will determine more details on charge speeds for specific models of EVs.

Removing more heat to shorten EV charging time

EV charging stations and other types of electronics rely on liquid cooling systems to remove heat from within their wires. Increasing the current through a charging cable using this method would require larger conductive wires and more liquid coolant, making the cable heavier and difficult for customers to handle.

For the past 37 years, Mudawar has been developing ways to more efficiently cool electronics by taking advantage of how liquid captures heat when boiled into a vapor. By capturing heat in both liquid and vapor forms, a liquid-to-vapor cooling system can remove at least 10 times more heat than pure liquid cooling.

These cooling benefits make it possible to use a smaller wire diameter inside the charging cable while dissipating a higher current. Research papers on the team’s experimental demonstration of the charging cable prototype and the cooling method it uses have been published in the International Journal of Heat and Mass Transfer.

Despite decades of research on liquid-to-vapor cooling, no industry has begun using these systems yet because studies like those conducted by Mudawar’s lab are needed to understand how to best implement the technology.

“The industry has a gap in knowledge and expertise needed to switch from pure liquid cooling to liquid phase change cooling. How do you design the system? What type of equations do you use to optimize it? But we do have this knowledge through our extensive research,” Mudawar said.

Beyond EVs: aircraft and spacecraft

Based on what Mudawar and his students observed from experimental demonstrations of their prototype, liquid-to-vapor cooling is so effective at removing large amounts of heat that EVs could charge in far less than five minutes using this technology.

“The industry doesn’t really need EVs to charge faster than five minutes, but we think we can increase the current even more by modifying both the state of the incoming liquid and the design of the cooling space around the conductor wires in the charging cable,” Mudawar said.

The prototype’s ability to remove far more heat than other chargers wasn’t a surprise to Mudawar. “My lab has developed solutions using liquid phase change technology for many applications, including in aerospace and defense. We knew how capable the technology is,” he said.

Similar to the EV charging cable prototype, the systems that Mudawar’s lab has designed for aircraft allow avionics to dissipate great amounts of heat, increasing their performance. Mudawar also has projects funded by NASA to boost the cooling capabilities of rocket engines and spacecraft.

The researchers have filed a patent application for their charging cable invention through the Purdue Research Foundation Office of Technology Commercialization and are seeking additional industry partners to continue the technology’s development.

https://www.purdue.edu/

ALPLA establishes new Asia-Pacific region

ALPLA establishes new Asia-Pacific region

Reorganisation enables bundling of competences and resources

Hard, 19 November 2021 – The ALPLA Group, the global packaging solutions and recycling specialist, has announced that it is strengthening its footprint in Asia. On 1 January 2022, the Asia-Pacific (APAC) head office in Singapore will go live, with a new region being created from a merger of the former regions North East Asia and South East Asia. It includes current operations in China, Thailand, Vietnam and the Philippines.

The APAC region will be managed by Roland Wallner, currently ALPLA Managing Director North East Asia. With 2,750 employees, ALPLA APAC is well situated to develop the packaging of tomorrow for the Asian market. Alongside extending the reach of Alpla’s industry-leading moulding technology, a strong focus lies on the further development of circular economy activities in the region.

ALPLA CEO Philipp Lehner states: ‘We are convinced that establishing this new regional organisation is the right step to support our ambitions in the region. It will especially enable us to develop market-leading products and services for our growing customer base in Asia.’

Roland Wallner, designated ALPLA Managing Director Region APAC, adds: ‘With this step we are bundling our extensive competences and resources in different markets of the region and aligning them in terms of strategic development, customer service, sales and purchasing.’

More information about the company: www.alpla.com